materials science

natural-piezoelectric-effect-may-build-gold-deposits

Natural piezoelectric effect may build gold deposits

chemistry, geology, gold, materials science, Quartz, Science / /

Building the bling —

How does an unreactive, barely soluble metal end up forming giant chunks?

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Image of a white rock with gold and black deposits speckled throughout it.

Enlarge / A lot of gold deposits are found embedded in quartz crystals.

One of the reasons gold is so valuable is because it is highly unreactive—if you make something out of gold, it keeps its lustrous radiance. Even when you can react it with another material, it’s also barely soluble, a combination that makes it difficult to purify away from other materials. Which is part of why a large majority of the gold we’ve obtained comes from deposits where it is present in large chunks, some of them reaching hundreds of kilograms.

Those of you paying careful attention to the previous paragraph may have noticed a problem here: If gold is so difficult to get into its pure form, how do natural processes create enormous chunks of it? On Monday, a group of Australian researchers published a hypothesis, and a bit of evidence supporting it. They propose that an earthquake-triggered piezoelectric effect essentially electroplates gold onto quartz crystals.

The hypothesis

Approximately 75 percent of the gold humanity has obtained has come from what are called orogenic gold deposits. Orogeny is a term for the tectonic processes that build mountains, and orogenic gold deposits form in the seams where two bodies of rock are moving past each other. These areas are often filled with hot hydrothermal fluids, and the heat can increase the solubility of gold from “barely there” to “extremely low,” meaning generally less than a single milligram in a liter of water.

The other striking thing about these deposits is that they’re generally associated with the mineral quartz, a crystalline form of silicon dioxide. And that fact formed the foundation for the new hypothesis, which brings together a number of topics that are generally considered largely unrelated.

It turns out that quartz is the only abundant mineral that’s piezoelectric, meaning that it generates a charge when it’s placed under strain. While you don’t need to understand why that’s the case to follow this hypothesis, the researchers’ explanation of the piezoelectric effect is remarkably cogent and clear, so I’ll just quote it here for people who want to come away from this having learned something: “Quartz is the only common mineral that forms crystals lacking a center of symmetry (non-centrosymmetric). Non-centrosymmetric crystals distorted under stress have an imbalance in their internal electric configuration, which produces an electrical potential—or voltage—across the crystal that is directly proportional to the applied mechanical force.”

Quartz happens to be an insulator, so this electric potential doesn’t easily dissipate on its own. It can, however, be eliminated through the transfer of electrons to or from any materials that touch the quartz crystals, including fluids. In practice, that means the charge can drive redox (reduction/oxidation) reactions in any nearby fluids, potentially neutralizing any dissolved ions and causing them to come out of solution.

This has the potential to be self-reinforcing. Once a small metal deposit forms on the surface of quartz, it will ease the exchange of electrons with the fluid in its immediate vicinity, meaning more metal will be deposited in the same location. This will also lower the concentration of the metal in the nearby solution, which will favor the diffusion of additional metal ions into the location, meaning that the fluid itself doesn’t need to keep circulating past the same spot.

Finally, the concept also needs a source of strain to generate the piezoelectric effect in the first place. But remember that this is all happening in an active fault zone, so strain is not in short supply.

And the evidence

Figuring out whether this happens in active fault zones would be extremely challenging for all sorts of reasons. But it’s relatively easy to dunk some quartz crystals in a solution containing gold and see what happens. So the latter is the route the Australians took.

The gold came in the form of either a solution of gold chloride ions or a suspension of gold nanoparticles. Quartz crystals were either pure quartz or obtained from a gold-rich area and already contained some small gold deposits. The crystals themselves were subject to strain at a frequency similar to that produced by small earthquakes, and the experiment was left to run for an hour.

An hour was enough to get small gold deposits to form on the pure quartz crystals, regardless of whether it was from dissolved gold or suspended gold nanoparticles. In the case of the naturally formed quartz, the gold ended up being deposited on the existing sites where gold metal is present, rather than forming additional deposits.

The researchers note that a lot of the quartz in deposits is disordered rather than in the form of single crystals. In disordered material, there are lots of small crystals oriented randomly, meaning the piezoelectric effect of any one of these crystals is typically canceled out by its neighbors. So, gold will preferentially form on single crystals, which also helps explain why it’s found in large lumps in these deposits.

So, this is a pretty compelling hypothesis—it explains something puzzling, relies on well-established processes, and has a bit of experimental support. Given that activity in active faults is likely to remain both slow and inaccessible, the next steps are probably going to involve getting longer-term information on the rate of deposition through this process and a physical comparison of these deposits with those found in natural settings.

Nature Geoscience, 2024. DOI: 10.1038/s41561-024-01514-1  (About DOIs).

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hydrogels-can-learn-to-play-pong

Hydrogels can learn to play Pong

active matter, chemistry, hydrogels, materials science, Physics, polymers, Pong, Science, smart materials / /

It’s all about the feedback loops —

Work could lead to new “smart” materials that can learn and adapt to their environment.

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This electroactive polymer hydrogel “learned” to play Pong. Credit: Cell Reports Physical Science/Strong et al.

Pong will always hold a special place in the history of gaming as one of the earliest arcade video games. Introduced in 1972, it was a table tennis game featuring very simple graphics and gameplay. In fact, it’s simple enough that even non-living materials known as hydrogels can “learn” to play the game by “remembering” previous patterns of electrical stimulation, according to a new paper published in the journal Cell Reports Physical Science.

“Our research shows that even very simple materials can exhibit complex, adaptive behaviors typically associated with living systems or sophisticated AI,” said co-author Yoshikatsu Hayashi, a biomedical engineer at the University of Reading in the UK. “This opens up exciting possibilities for developing new types of ‘smart’ materials that can learn and adapt to their environment.”

Hydrogels are soft, flexible biphasic materials that swell but do not dissolve in water. So a hydrogel may contain a large amount of water but still maintain its shape, making it useful for a wide range of applications. Perhaps the best-known use is soft contact lenses, but various kinds of hydrogels are also used in breast implants, disposable diapers, EEG and ECG medical electrodes, glucose biosensors, encapsulating quantum dots, solar-powered water purification, cell cultures, tissue engineering scaffolds, water gel explosives, actuators for soft robotics, supersonic shock-absorbing materials, and sustained-release drug delivery systems, among other uses.

In April, Hayashi co-authored a paper showing that hydrogels can “learn” to beat in rhythm with an external pacemaker, something previously only achieved with living cells. They exploited the intrinsic ability of the hydrogels to convert chemical energy into mechanical oscillations, using the pacemaker to apply cyclic compressions. They found that when the oscillation of a gel sample matched the harmonic resonance of the pacemaker’s beat, the system kept a “memory” of that resonant oscillation period and could retain that memory even when the pacemaker was turned off. Such hydrogels might one day be a useful substitute for heart research using animals, providing new ways to research conditions like cardiac arrhythmia.

For this latest work, Hayashi and co-authors were partly inspired by a 2022 study in which brain cells in a dish—dubbed DishBrain—were electrically stimulated in such a way as to create useful feedback loops, enabling them to “learn” to play Pong (albeit badly). As Ars Science Editor John Timmer reported at the time:

Pong proved to be an excellent choice for the experiments. The environment only involves a couple of variables: the location of the paddle and the location of the ball. The paddle can only move along a single line, so the motor portion of things only needs two inputs: move up or move down. And there’s a clear reward for doing things well: you avoid an end state where the ball goes past the paddles and the game stops. It is a great setup for testing a simple neural network.

Put in Pong terms, the sensory portion of the network will take the positional inputs, determine an action (move the paddle up or down), and then generate an expectation for what the next state will be. If it’s interpreting the world correctly, that state will be similar to its prediction, and thus the sensory input will be its own reward. If it gets things wrong, then there will be a large mismatch, and the network will revise its connections and try again.

There were a few caveats—even the best systems didn’t play Pong all that well—but the approach mostly worked. Those systems comprising either mouse or human neurons saw the average length of Pong rallies increase over time, indicating they might be learning the game’s rules. Systems based on non-neural cells, or those lacking a reward system, didn’t see this sort of improvement. The findings provided some evidence that neural networks formed from actual neurons spontaneously develop the ability to learn. And that could explain some of the learning capabilities of actual brains, where smaller groups of neurons are organized into functional units.

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Silicon plus perovskite solar reaches 34 percent efficiency

green, green energy, materials science, perovskites, photovoltaics, Science, solar power, Sustainability / /
Solar panels with green foliage behind them, and a diagram of a chemical's structure in the foreground.

Enlarge / Some solar panels, along with a diagram of a perovskite’s crystal structure.

As the price of silicon panels has continued to come down, we’ve reached the point where they’re a small and shrinking cost of building a solar farm. That means that it might be worth spending more to get a panel that converts more of the incoming sunlight to electricity, since it allows you to get more out of the price paid to get each panel installed. But silicon panels are already pushing up against physical limits on efficiency. Which means our best chance for a major boost in panel efficiency may be to combine silicon with an additional photovoltaic material.

Right now, most of the focus is on pairing silicon with a class of materials called perovskites. Perovskite crystals can be layered on top of silicon, creating a panel with two materials that absorb different areas of the spectrum—plus, perovskites can be made from relatively cheap raw materials. Unfortunately, it has been difficult to make perovskites that are both high-efficiency and last for the decades that the silicon portion will.

Lots of labs are attempting to change that, though. And two of them reported some progress this week, including a perovskite/silicon system that achieved 34 percent efficiency.

Boosting perovskite stability

Perovskites are an entire class of materials that all form the same crystal structure. So, there is plenty of flexibility when it comes to the raw materials being used. Perovskite-based photovoltaics are typically formed by what’s called solution processing, in which all the raw materials are dissolved in a liquid that’s then layered on top of the panel-to-be, allowing perovskite crystals to form across its entire surface. Which is great, except that this process tends to form multiple crystals with different orientations on a single surface, decreasing performance.

Adding to the problems, perovskites are also not especially stable. They’re usually made of a combination of positively and negatively charged ions, and these have to be present in the right ratios to form a perovskite. However, some of these individual ions can diffuse over time, disrupting the crystal structure. Harvesting solar energy, which involves the material absorbing lots of energy, makes matters worse by heating the material, which increases the rate of diffusion.

Combined, these factors sap the efficiency of perovskite solar cells and mean that none lasts nearly as long as a sheet of silicon. The new works tackle these issues from two very different directions.

The first of the new papers tackles stability by using the flexibility of perovskites to incorporate various ions. The researchers started by using a technique called density functional theory to model how different molecules would behave when placed into a spot normally occupied by a positively charged ion. And the modeling got them excited about a molecule called tetrahydrotriazinium, which has a six-atom ring composed of alternating carbon and nitrogen atoms. The regular placement of nitrogens around the ring allows it to form regular interactions with neighboring atoms in the crystal structure.

Tetrahydrotriazinium has a neutral charge when only two of the nitrogens have hydrogens attached to them. But it typically grabs a charged hydrogen (effectively, a proton) out of solution, giving it a net positive charge. This leaves each of its three nitrogens associated with a hydrogen and allows the positive charge to be distributed among them. That makes this interaction incredibly strong, meaning that the hydrogens are extremely unlikely to drift off, which also stabilizes the crystal structure.

So, this should make perovskites much, much more stable. The only problem? Tetrahydrotriazinium tends to react with lots of other chemicals, so it’s difficult to provide as a raw material for the perovskite-forming solution.

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researchers-build-ultralight-drone-that-flies-with-onboard-solar

Researchers build ultralight drone that flies with onboard solar

drone, materials science, Physics, robotics, Science, solar power / /

Where does it go? It goes up! —

Bizarre design uses a solar-powered motor that’s optimized for weight.

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Image of a metallic object composed from top to bottom of a propeller, a large cylinder with metallic panels, a stalk, and a flat slab with solar panels and electronics.

Enlarge / The CoulombFly doing its thing.

On Wednesday, researchers reported that they had developed a drone they’re calling the CoulombFly, which is capable of self-powered hovering for as long as the Sun is shining. The drone, which is shaped like no aerial vehicle you’ve ever seen before, combines solar cells, a voltage converter, and an electrostatic motor to drive a helicopter-like propeller—with all components having been optimized for a balance of efficiency and light weight.

Before people get excited about buying one, the list of caveats is extensive. There’s no onboard control hardware, and the drone isn’t capable of directed flight anyway, meaning it would drift on the breeze if ever set loose outdoors. Lots of the components appear quite fragile, as well. However, the design can be miniaturized, and the researchers built a version that weighs only 9 milligrams.

Built around a motor

One key to this development was the researchers’ recognition that most drones use electromagnetic motors, which involve lots of metal coils that add significant weight to any system. So, the team behind the work decided to focus on developing a lightweight electrostatic motor. These rely on charge attraction and repulsion to power the motor, as opposed to magnetic interactions.

The motor the researchers developed is quite large relative to the size of the drone. It consists of an inner ring of stationary charged plates called the stator. These plates are composed of a thin carbon-fiber plate covered in aluminum foil. When in operation, neighboring plates have opposite charges. A ring of 64 rotating plates surrounds that.

The motor starts operating when the plates in the outer ring are charged. Since one of the nearby plates on the stator will be guaranteed to have the opposite charge, the pull will start the rotating ring turning. When the plates of the stator and rotor reach their closest approach, thin wires will make contact, allowing charges to transfer between them. This ensures that the stator and rotor plates now have the same charge, converting the attraction to a repulsion. This keeps the rotor moving, and guarantees that the rotor’s plate now has the opposite charge from the next stator plate down the line.

These systems typically require very little in the way of amperage to operate. But they do require a large voltage difference between the plates (something we’ll come back to).

When hooked up to a 10-centimeter, eight-bladed propeller, the system could produce a maximum lift of 5.8 grams. This gave the researchers clear weight targets when designing the remaining components.

Ready to hover

The solar power cells were made of a thin film of gallium arsenide, which is far more expensive than other photovoltaic materials, but offers a higher efficiency (30 percent conversion compared to numbers that are typically in the mid-20s). This tends to provide the opposite of what the system needs: reasonable current at a relatively low voltage. So, the system also needed a high-voltage power converter.

Here, the researchers sacrificed efficiency for low weight, arranging a bunch of voltage converters in series to create a system that weighs just 1.13 grams, but steps the voltage up from 4.5 V all the way to 9.0 kV. But it does so with a power conversion efficiency of just 24 percent.

The resulting CoulombFly is dominated by the large cylindrical motor, which is topped by the propeller. Suspended below that is a platform with the solar cells on one side, balanced out by the long, thin power converter on the other.

Meet the CoulombFly.

To test their system, the researchers simply opened a window on a sunny day in Beijing. Starting at noon, the drone took off and hovered for over an hour, and all indications are that it would have continued to do so for as long as the sunlight provided enough power.

The total system required just over half a watt of power to stay aloft. Given a total mass of 4 grams, that works out to a lift-to-power efficiency of 7.6 grams per watt. But a lot of that power is lost during the voltage conversion. If you focus on the motor alone, it only requires 0.14 watts, giving it a lift-to-power efficiency of over 30 grams per watt.

The researchers provide a long list of things they could do to optimize the design, including increasing the motor’s torque and propeller’s lift, placing the solar cells on structural components, and boosting the efficiency of the voltage converter. But one thing they don’t have to optimize is the vehicle’s size since they already built a miniaturized version that’s only 8 millimeters high and weighs just 9 milligrams but is able to generate a milliwatt of power that turns its propeller at over 15,000 rpm.

Again, all this is done without any onboard control circuitry or the hardware needed to move the machine anywhere—they’re basically flying these in cages to keep them from wandering off on the breeze. But there seems to be enough leeway in the weight that some additional hardware should be possible, especially if they manage some of the potential optimizations they mentioned.

Nature, 2024. DOI: 10.1038/s41586-024-07609-4  (About DOIs).

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“energy-smart”-bricks-need-less-power-to-make,-are-better-insulation

“Energy-smart” bricks need less power to make, are better insulation

bricks, green, materials science, recycling, Science, Sustainability, waste / /
Image of a person holding a bag full of dirty looking material with jagged pieces in it.

Enlarge / Some of the waste material that ends up part of these bricks.

Seamus Daniel, RMIT University

Researchers at the Royal Melbourne Institute of Technology (RMIT) in Australia have developed special “energy-smart bricks” that can be made by mixing clay with glass waste and coal ash. These bricks can help mitigate the negative effects of traditional brick manufacturing, an energy-intensive process that requires large-scale clay mining, contributes heavily to CO2 emissions, and generates a lot of air pollution.

According to the RMIT researchers, “Brick kilns worldwide consume 375 million tonnes (~340 million metric tons) of coal in combustion annually, which is equivalent to 675 million tonnes of CO2 emission (~612 million metric tons).” This exceeds the combined annual carbon dioxide emissions of 130 million passenger vehicles in the US.

The energy-smart bricks rely on a material called RCF waste. It mostly contains fine pieces of glass (92 percent) left over from the recycling process, along with ceramic materials, plastic, paper, and ash. Most of this waste material generally ends up in landfills, where it can cause soil and water degradation. However, the study authors note, “The utilization of RCF waste in fired-clay bricks offers a potential solution to the increasing global waste crisis and reduces the burden on landfills.”

What makes the bricks “energy-smart”

Compared to traditional bricks, the newly developed energy-smart bricks have lower thermal conductivity: They retain heat longer and undergo more uniform heating. This means they can be manufactured at lower firing temperatures. For instance, while regular clay bricks are fired (a process during which bricks are baked in a kiln, so they become hard and durable) at 1,050° C, energy-smart bricks can achieve the required hardness at 950° C, saving 20 percent of the energy needed for traditional brickmaking.

Based on bricks produced in their lab, they estimated that “each firing cycle led to a potential value of up to $158,460 through a reduction of 417 tonnes of CO2, resulting from a 9.5 percent reduction in firing temperature.” So basically, if a manufacturer switches from regular clay bricks to energy-smart bricks, it will end up saving thousands of dollars on its power bill, and its kilns will release less CO2 into Earth’s atmosphere. Scaled up to the estimated 1.4 trillion bricks made each year, the savings are substantial.

But brick manufacturers aren’t the only ones who benefit. “Bricks characterized by low thermal conductivity contribute to efficient heat storage and absorption, creating a cooler environment during summer and a warmer comfort during winter. This advantage translates into energy savings for air conditioning, benefiting the occupants of the house or building,” the study authors explained.

Tests conducted by the researchers suggest that the residents of a single-story house built using energy-smart bricks will save up to 5 percent on their energy bills compared to those living in a house made with regular clay bricks.

“Energy-smart” bricks need less power to make, are better insulation Read More »

researchers-make-a-plastic-that-includes-bacteria-that-can-digest-it

Researchers make a plastic that includes bacteria that can digest it

bacteria, Biology, chemistry, evolution, materials science, plastics, Science / /

It’s alive! —

Bacterial spores strengthen the plastic, then revive to digest it in landfills.

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Image of two containers of dirt, one with a degraded piece of plastic in it.

Han Sol Kim

One reason plastic waste persists in the environment is because there’s not much that can eat it. The chemical structure of most polymers is stable and different enough from existing food sources that bacteria didn’t have enzymes that could digest them. Evolution has started to change that situation, though, and a number of strains have been identified that can digest some common plastics.

An international team of researchers has decided to take advantage of those strains and bundle plastic-eating bacteria into the plastic. To keep them from eating it while it’s in use, the bacteria is mixed in as inactive spores that should (mostly—more on this below) only start digesting the plastic once it’s released into the environment. To get this to work, the researchers had to evolve a bacterial strain that could tolerate the manufacturing process. It turns out that the evolved bacteria made the plastic even stronger.

Bacteria meet plastics

Plastics are formed of polymers, long chains of identical molecules linked together by chemical bonds. While they can be broken down chemically, the process is often energy-intensive and doesn’t leave useful chemicals behind. One alternative is to get bacteria to do it for us. If they’ve got an enzyme that breaks the chemical bonds of a polymer, they can often use the resulting small molecules as an energy source.

The problem has been that the chemical linkages in the polymers are often distinct from the chemicals that living things have come across in the past, so enzymes that break down polymers have been rare. But, with dozens of years of exposure to plastics, that’s starting to change, and a number of plastic-eating bacterial strains have been discovered recently.

This breakdown process still requires that the bacteria and plastics find each other in the environment, though. So a team of researchers decided to put the bacteria in the plastic itself.

The plastic they worked with is called thermoplastic polyurethane (TPU), something you can find everywhere from bicycle inner tubes to the coating on your ethernet cables. Conveniently, there are already bacteria that have been identified that can break down TPU, including a species called Bacillus subtilis, a harmless soil bacterium that has also colonized our digestive tracts. B. subtilis also has a feature that makes it very useful for this work: It forms spores.

This feature handles one of the biggest problems with incorporating bacteria into materials: The materials often don’t provide an environment where living things can thrive. Spores, on the other hand, are used by bacteria to wait out otherwise intolerable conditions, and then return to normal growth when things improve. The idea behind the new work is that B. subtilis spores remain in suspended animation while the TPU is in use and then re-activate and digest it once it’s disposed of.

In practical terms, this works because spores only reactivate once nutritional conditions are sufficiently promising. An Ethernet cable or the inside of a bike tire is unlikely to see conditions that will wake the bacteria. But if that same TPU ends up in a landfill or even the side of the road, nutrients in the soil could trigger the spores to get to work digesting it.

The researchers’ initial problem was that the manufacturing of TPU products usually involves extruding the plastic at high temperatures, which are normally used to kill bacteria. In this case, they found that a typical manufacturing temperature (130° C) killed over 90 percent of the B. subtilis spores in just one minute.

So, they started out by exposing B. subtilis spores to lower temperatures and short periods of heat that were enough to kill most of the bacteria. The survivors were grown up, made to sporulate, and then exposed to a slightly longer period of heat or even higher temperatures. Over time, B. subtilis evolved the ability to tolerate a half hour of temperatures that would kill most of the original strain. The resulting strain was then incorporated into TPU, which was then formed into plastics through a normal extrusion process.

You might expect that putting a bunch of biological material into a plastic would weaken it. But the opposite turned out to be true, as various measures of its tensile strength showed that the spore-containing plastic was stronger than pure plastic. It turns out that the spores have a water-repelling surface that interacts strongly with the polymer strands in the plastic. The heat-resistant strain of bacteria repelled water even more strongly, and plastics made with these spores was tougher still.

To simulate landfilling or litter with the plastic, the researchers placed them in compost. Even without any bacteria, there were organisms present that could degrade it; by five months in the compost, plain TPU lost nearly half its mass. But with B. subtilis spores incorporated, the plastic lost 93 percent of its mass over the same time period.

This doesn’t mean our plastics problem is solved. Obviously, TPU breaks down relatively easily. There are lots of plastics that don’t break down significantly, and may not be compatible with incorporating bacterial spores. In addition, it’s possible that some TPU uses would expose the plastic to environments that would activate the spores—something like food handling or buried cabling. Still, it’s possible this new breakdown process can provide a solution in some cases, making it worth exploring further.

Nature Communications, 2024. DOI: 10.1038/s41467-024-47132-8  (About DOIs).

Listing image by Han Sol Kim

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this-stretchy-electronic-material-hardens-upon-impact-just-like-“oobleck”

This stretchy electronic material hardens upon impact just like “oobleck”

conductive polymers, flexible electronics, kitchen science, materials science, oobleck, Physics, polymers, Science / /

a flexible alternative —

Researchers likened material’s structure to a big bowl of spaghetti and meatballs.

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This flexible and conductive material has “adaptive durability,” meaning it gets stronger when hit.

Enlarge / This flexible and conductive material has “adaptive durability,” meaning it gets stronger when hit.

Yue (Jessica) Wang

Scientists are keen to develop new materials for lightweight, flexible, and affordable wearable electronics so that, one day, dropping our smartphones won’t result in irreparable damage. One team at the University of California, Merced, has made conductive polymer films that actually toughen up in response to impact rather than breaking apart, much like mixing corn starch and water in appropriate amounts produces a slurry that is liquid when stirred slowly but hardens when you punch it (i.e., “oobleck”). They described their work in a talk at this week’s meeting of the American Chemical Society in New Orleans.

“Polymer-based electronics are very promising,” said Di Wu, a postdoc in materials science at UCM. “We want to make the polymer electronics lighter, cheaper, and smarter. [With our] system, [the polymers] can become tougher and stronger when you make a sudden movement, but… flexible when you just do your daily, routine movement. They are not constantly rigid or constantly flexible. They just respond to your body movement.”

As we’ve previously reported, oobleck is simple and easy to make. Mix one part water to two parts corn starch, add a dash of food coloring for fun, and you’ve got oobleck, which behaves as either a liquid or a solid, depending on how much stress is applied. Stir it slowly and steadily and it’s a liquid. Punch it hard and it turns more solid under your fist. It’s a classic example of a non-Newtonian fluid.

In an ideal fluid, the viscosity largely depends on temperature and pressure: Water will continue to flow regardless of other forces acting upon it, such as being stirred or mixed. In a non-Newtonian fluid, the viscosity changes in response to an applied strain or shearing force, thereby straddling the boundary between liquid and solid behavior. Stirring a cup of water produces a shearing force, and the water shears to move out of the way. The viscosity remains unchanged. But for non-Newtonian fluids like oobleck, the viscosity changes when a shearing force is applied.

Ketchup, for instance, is a shear-thickening non-Newtonian fluid, which is one reason smacking the bottom of the bottle doesn’t make the ketchup come out any faster; the application of force increases the viscosity. Yogurt, gravy, mud, and pudding are other examples. And so is oobleck. (The name derives from a 1949 Dr. Seuss children’s book, Bartholomew and the Oobleck.) By contrast, non-drip paint exhibits a “shear-thinning” effect, brushing on easily but becoming more viscous once it’s on the wall. Last year, MIT scientists confirmed that the friction between particles was critical to that liquid-to-solid transition, identifying a tipping point when the friction reached a certain level and the viscosity abruptly increased.

Wu works in the lab of materials scientist Yue (Jessica) Wang, who decided to try to mimic the shear-thickening behavior of oobleck in a polymer material. Flexible polymer electronics are usually made by linking together conjugated conductive polymers, which are long and thin, like spaghetti. But these materials will still break apart in response to particularly large and/or rapid impacts.

So Wu and Wang decided to combine the spaghetti-like polymers with shorter polyaniline molecules and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate, or PEDOT:PSS—four different polymers in all. Two of the four have a positive charge, and two have a negative charge. They used that mixture to make stretchy films and then tested the mechanical properties.

Lo and behold, the films behaved very much like oobleck, deforming and stretching in response to impact rather than breaking apart. Wang likened the structure to a big bowl of spaghetti and meatballs since the positively charged molecules don’t like water and therefore cluster into ball-like microstructures. She and Wu suggest that those microstructures absorb impact energy, flattening without breaking apart. And it doesn’t take much PEDOT:PSS to get this effect: just 10 percent was sufficient.

Further experiments identified an even more effective additive: positively charged 1,3-propanediamine nanoparticles. These particles can weaken the “meatball” polymer interactions just enough so that they can deform even more in response to impacts, while strengthening the interactions between the entangled long spaghetti-like polymers.

The next step is to apply their polymer films to wearable electronics like smartwatch bands and sensors, as well as flexible electronics for monitoring health. Wang’s lab has also experimented with a new version of the material that would be compatible with 3D printing, opening up even more opportunities. “There are a number of potential applications, and we’re excited to see where this new, unconventional property will take us,” said Wang.

This stretchy electronic material hardens upon impact just like “oobleck” Read More »

building-robots-for-“zero-mass”-space-exploration

Building robots for “Zero Mass” space exploration

materials science, robotics, Science, Space, Space exploration / /
A robot performing construction on the surface of the moon against the black backdrop of space.

Sending 1 kilogram to Mars will set you back roughly $2.4 million, judging by the cost of the Perseverance mission. If you want to pack up supplies and gear for every conceivable contingency, you’re going to need a lot of those kilograms.

But what if you skipped almost all that weight and only took a do-it-all Swiss Army knife instead? That’s exactly what scientists at NASA Ames Research Center and Stanford University are testing with robots, algorithms, and highly advanced building materials.

Zero mass exploration

“The concept of zero mass exploration is rooted in self-replicating machines, an engineering concept John von Neumann conceived in the 1940s”, says Kenneth C. Cheung, a NASA Ames researcher. He was involved in the new study published recently in Science Robotics covering self-reprogrammable metamaterials—materials that do not exist in nature and have the ability to change their configuration on their own. “It’s the idea that an engineering system can not only replicate, but sustain itself in the environment,” he adds.

Based on this concept, Robert A. Freitas Jr. in the 1980s proposed a self-replicating interstellar spacecraft called the Von Neumann probe that would visit a nearby star system, find resources to build a copy of itself, and send this copy to another star system. Rinse and repeat.

“The technology of reprogrammable metamaterials [has] advanced to the point where we can start thinking about things like that. It can’t make everything we need yet, but it can make a really big chunk of what we need,” says Christine E. Gregg, a NASA Ames researcher and the lead author of the study.

Building blocks for space

One of the key problems with Von Neumann probes was that taking elements found in the soil on alien worlds and processing them into actual engineering components was resource-intensive and required huge amounts of energy. The NASA Ames team solved that with using prefabricated “voxels”—standardized reconfigurable building blocks.

The system derives its operating principles from the way nature works on a very fundamental level. “Think how biology, one of the most scalable systems we have ever seen, builds stuff,” says Gregg. “It does that with building blocks. There are on the order of 20 amino acids which your body uses to make proteins to make 200 different types of cells and then combines trillions of those cells to make organs as complex as my hair and my eyes. We are using the same strategy,” she adds.

To demo this technology, they built a set of 256 of those blocks—extremely strong 3D structures made with a carbon-fiber-reinforced polymer called StattechNN-40CF. Each block had fastening interfaces on every side that could be used to reversibly attach them to other blocks and form a strong truss structure.

A 3×3 truss structure made with these voxels had an average failure load of 900 Newtons, which means it could hold over 90 kilograms despite being incredibly light itself (its density is just 0.0103 grams per cubic centimeter). “We took these voxels out in backpacks and built a boat, a shelter, a bridge you could walk on. The backpacks weighed around 18 kilograms. Without technology like that, you wouldn’t even think about fitting a boat and a bridge in a backpack,” says Cheung. “But the big thing about this study is that we implemented this reconfigurable system autonomously with robots,” he adds.

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a-locally-grown-solution-for-period-poverty

A locally grown solution for period poverty

agave, agriculture, materials science, Science, Sustainability / /

Absorbant agave —

A Kenyan tinkerer and Stanford engineer team up to make maxi pads from agave fibers.

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Image of rows of succulents with long spiky leaves and large flower stalks.

Enlarge / Sisal is an invasive species that is also grown agriculturally.

Women and girls across much of the developing world lack access to menstrual products. This means that for at least a week or so every month, many girls don’t go to school, so they fall behind educationally and often never catch up economically. 

Many conventional menstrual products have traditionally been made of hydrogels made from toxic petrochemicals, so there has been a push to make them out of biomaterials. But this usually means cellulose from wood, which is in high demand for other purposes and isn’t readily available in many parts of the globe. So Alex Odundo found a way to solve both of these problems: making maxi pads out of sisal, a drought-tolerant agave plant that grows readily in semi-arid climates like his native Kenya.

Putting an invasive species to work

Sisal is an invasive plant in rural Kenya, where it is often planted as livestock fencing and feedstock. It doesn’t require fertilizer, and its leaves can be harvested all year long over a five- to seven-year span. Odundo and his partners in Manu Prakash’s lab at Stanford University developed a process to generate soft, absorbent material from the sisal leaves. It relies on treatment with dilute peroxyformic acid (1 percent) to increase its porosity, followed by washing in sodium hydroxide (4 percent) and then spinning in a tabletop blender to enhance porosity and make it softer. 

They tested their fibers with a mixture of water mixed with glycerol—to make it thicker, like blood—and found that it is as absorbent as the cotton used in commercially available maxi pads. It was also as absorbent as wood pulp and more absorbent than fibers prepared from other biomaterials, including hemp and flax. Moreover, their process is less energy-intensive than conventional processing procedures, which are typically performed at higher temperatures and pressures. 

In a cradle-to-gate carbon footprint life cycle analysis, including sisal cultivation, harvesting, manufacturing, and transportation, sisal cellulose microfiber production fared roughly the same as production of cellulose microfiber from wood and much better than that from cotton in terms of both carbon footprint and water consumption, possibly because cotton requires so much upstream fertilizer. Much of the footprint comes from transportation, highlighting how useful it can be to make products like this in the same communities that need them.

Science for the greater good

This is not Odundo’s first foray into utilizing sisal; at Olex Techno Enterprises in Kisumu, Kenya, he has been making machines to turn sisal leaves into rope for over 10 years. This benefits local farmers since sisal rope and even sisal fibers sell for ten times as much as sisal leaves. In addition to making maxi pads, Odundo also built a stove that burns sawdust, rice husks, and other biodegradable waste products. 

By reducing wood stoves, he is reducing deforestation and improving the health of the women who breathe in the smoke of the cookfires. Adoption of such stoves have been a goal of environmentalists for years, and although a number of prototypes have been developed by mostly male engineers in developed countries, they have not been widely used because they are not that practical or appealing to the mostly female cooks in developing countries—the people who actually need to cook with them, yet were not consulted in their design.

Manu Prakash’s lab’s website proclaims that “we are dedicated toward inventing and distributing ‘frugal science’ tools to democratize access to science.” Partnering with Alex Odundo to manufacture menstrual products in the low-income rural communities that most need them seems like the apotheosis of that goal.

Communications Engineering, 2023. DOI:  10.1038/s44172-023-00130-y

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